What About Lye?  
Won't it harm my skin?

 

Our ingredients list includes the words, "saponified oils," which actually means that the oils and butters are mixed with lye water.  We receive many questions about whether there is lye (sodium hydroxide) in our soap. The simple answer is "No." While all real soap must be made with lye (anything made without lye is a detergent and not a soap), no lye remains in our finished product.
 


Red Rose & Buttermilk Soap

 

SAPONIFICATION: The Chemical Reaction

Lye is an alkali and the oils are fatty acids.
Once we select the oils and mix them with sodium hydroxide and a liquid,
the molecules combine, a chemical reaction occurs, called
saponification
(pictured below),
and a totally different substance is created -- SOAP!


picture from The Soap & Detergent Association website

The Reactants (what we start with)

 

The Products (what we end up with)
 

Triglycerides     +      Alkali            

=

 Neat Soap    +     Water    +    Glycerine
Triglycerides are what make up the oils and butters we use.  A triglyceride, is a chemical compound formed from one molecule of glycerol and three fatty acid molecules.

The alkali is the lye mixed with rainwater, tea, goat milk, juice, etc.

  When mixed together the chemical reaction (saponification) results in...

neat soap: the saponified oils

water
: which evaporates as the soap cures

glycerine:
In commercial soap, the natural glycerin removed from the soap and used in moisturizers and other cosmetics where it commands a higher price.  Our handmade soaps retains the glycerin which occurs naturally in the soap making process.

Notice there is no LYE on the product side of the equation!  No lye remains in our finished product!

SUPERFATTING

Superfatting is the process of adding extra fats (oils or butters) when formulating a soap recipe, so there is more fat in the mixture than the lye can react with during the chemical reaction.

If you look at the colored picture of the chemical reaction above, in addition to "soap," glycerine, and water, Chagrin Valley Soaps also contain free oils which have been left unchanged by the saponification process and add extra moisturizing properties to our soaps and shampoos!

 

WE SUPERFAT
all of our
SOAPS & SHAMPOOS

If you are still not convinced here is an example of another chemical reaction.  The element sodium (Na) is a highly reactive element that explodes if it touches water.  The element chlorine (Cl) is a deadly poisonous gas.  But when they come together in a chemical reaction a totally different substance is created -- table salt (NaCl)!


Chagrin Valley Soap & Craft uses computerized software to determine just the right amount of lye needed--
so there is NO lye left in a bar of Ida’s Handcrafted Soap, just fabulous all natural soap.
 

Interesting Note About Lye!

Lye has many uses in the food industry. The secret to great pretzels is a lye bath!  Lye gives pretzels their characteristic flavor, crispiness, and glossy finish.  Hominy is dried corn kernels reconstituted by soaking them in lye water until the germ is removed.   Lye may also be used in the preparation of olives and pickles.
 

Click here to learn more about how we make Ida's Handcrafted Soap
at Chagrin Valley Soap & Craft Company.

 

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